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Don
Zebolsky is interested in calculating volumes, enthalpies and solubilities
for supercritical fluid mixtures. Calculations are with van der
Waals type equations of state that replace the excluded volume term
with hard sphere expressions, and add temperature-dependent attractive
terms with molecular meaning. Computer programs are written to test
these features and used to compare experimental data in the literature
with predicitons and curve fits. Don Zebolsky is also trying to
observe interactions in solution with differential scanning calorimetry
and osmometry.
Selected recent publications:
1. Zebolsky, D.M.; Renuncio, J.A.R. "Correlation and Prediction
of Critical and Supercritical Excess Enthalpies Using Equations
of State," J. Supercrit.
Fluids 1994, 7, 31-41.
2. Zebolsky, Don M. "Excess enthalpies for inorganic liquids
with supercritical carbon dioxide: Equation of state correlations,"
Thermochimica Acta 1997, 292, 51-57.
1. Zebolsky, Don M.; "Comparisons of Supercritical Properties
from an Equation of State with a Hard-sphere Repulsive Pressure
Term and from the Peng-Robinson Equation of State," Industrial
and Engineering Chemistry Research 2000, 39(10), 3521-3527.
2. Geng, Xindu; Zebolsky, Don M.; "The SDM Model and Langmuir
and Freundlich Adsorption," Journal of Chemical Education
2002, 79(3), 385-388.
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